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化学系副教授。桂林工学院本科毕业,河南师范大学理学硕士,南开大学理学博士,北京大学化学与分子工程学院博士后。研究领域为多相催化,重点关注催化剂表面结构与催化活性的构效关系,以及探索化学反应的催化机理。目前已在SCI期刊发表论文90多篇,主持和参研国家和省部级项目近10项。主讲课程有《物理化学》(本科)、《晶体化学基础》(本科),《结晶化学导论》(研究生),已参编《物理化学》、《无机化学》等教材4部。 |
觊发k8旗舰厅:联系方式
办公地点:虎溪校区理科楼LC416;实验室LC334
电子邮箱:gaowl@cqu.edu.cn 电话:13452079116
觊发k8旗舰厅:研究方向
觊发k8旗舰厅:代表性论文、专著和专利
1) D. Wang, Y. Yang, F. H. Zhang, P. F. Jiang, W. L Gao,* R. H. Cong, T. Yang*, Ring-Opening Hydration of Epoxides into Diols with a Low Water?Epoxide Ratio Catalyzed by a Fe-Incorporated Octahedra-Based Molecular Sieve, J. Phys. Chem. C 2021, 125, 13291?13303
2) W. L. Wang, Y. He, J. K. He, Y. L. Dang, T. Kankanmkapuge, W. L. Gao,* R. H. Cong, S. L. Suib,* T. Yang,* Identification of key oxidative intermediates and the function of chromium dopants in PKU-8: catalytic dehydrogenation of sec-alcohols with tert-butylhydroperoxide,Catal. Sci. Technol., 2021, 11, 1365
3) Y. Yang, D. Wang, P. F. Jiang, W. L. Gao,*, R. H. Cong, T. Yang,* Structure-induced Lewis-base Ga4B2O9 and its superior performance in Knoevenagel condensation reaction,Mol. Catal. 490 (2020) 110914
4) W. L. Wang, C. M. Zeng, Y. Yang, P. F. Jiang, W. L.Gao,* R. H. Cong, T. Yang,* Continuous solid solutions constructed from two isostructural octahedron-based molecular sieves: preparation, acidity regulation and catalytic application in Strecker reactions,New J. Chem., 2019, 43, 18184
5) H. W. Chen, W. L.Wang, Y.Yang, P. F. Jiang, W. L. Gao,* R. H. Cong, T. Yang,Solvent effect on the formation of active free radicals from H2O2 catalyzed by Cr-substituted PKU-1 aluminoborate: Spectroscopic investigation and reaction mechanism,Applied Catal. A, 588 (2019) 117283
6) S. X. Hu, W. L. Wang, M. F. Yue, G. J. Wang, W. L. Gao,* R. H. Cong, T. Yang*,Strong Lewis Base Ga4B2O9: Ga?O Connectivity Enhanced Basicity and Its Applications in the Strecker Reaction and Catalytic Conversion of n?Propanol,ACS Appl. Mater. Interfaces 2018, 10, 15895?15904
7) W. L. Wang, S. X. Hu, L. J. Li, W. L. Gao*, R. H. Cong, T. Yang*, Octahedral-based redox molecular sieve M-PKU-1: isomorphous metal-substitution, catalytic oxidation of sec-alcohol and related catalytic mechanism, J. Catal. 2017, 352, 130-141
8) W. L. Wang, S. Y. Zhang, S. X. Hu, D. Wang, W. L. Gao*, R. H. Cong, T. Yang*, Octahedron-based redox molecular sieves M-PKU-1 (M = Cr, Fe): A novel dual-centered solid acid catalyst for heterogeneously catalyzed Strecker reaction, Applied Catal. A: 542 (2017) 240-251
9) F. H. Zhang, W. L. Wang, S. X. Hu, X. T. Ma, W. L. Gao*, R. H. Cong, T. Yang*, “A nanosized aluminoborate (PKU-5) with Cr-centered octahedral framework: solid-phase synthesis, characterizations and catalytic ammoximation of cyclohexanone to cyclohexanone azine”, Applied Catal. A: 531 (2017) 60–68.
10) G. J. Wang, W. L. Wang, F. H. Zhang, W. L. Gao,* R. H. Cong, T. Yang,* “Octahedron-based gallium borates (Ga-PKU-1) with open-framework: acidity, catalytic dehydration and structure-activity relationship”, Catal. Sci. Technol., 2016, 6, 5992–6001.
11) W. L. Wang, Y. Wang, B. Wu, R. H. Cong, W. L. Gao,* B. Qin,* T. Yang, “Octahedra-based Molecular Sieve Alunimoborate (PKU-1) as Solid Acid for Heterogeneously Catalyzed Strecker Reaction” Catal. Commun. 2015, 58, 174-178.
12) J. Xiang, Q. Q. Li, G. J. Wang, J. Ju, R. H. Cong, W. Yin, W. L. Gao,* T. Yang,* “(Al1-xCrx)4B6O15 (0.08 ≤ x ≤ 0.14): Metal Borates Catalyze the Dehydration of Methanol into Dimethyl Ether” Mater. Res. Bull. 2015, 65, 279-286.
13) R. Wang, M. F. Yue, R. H. Cong, W. L. Gao,* T. Yang,* “Photocatalytic reduction of nitrate over chalcopyrite CuFe0.7Cr0.3S2 with high N2 selectivity”, J. Alloy Compd. 2015, 651, 731-736.
14) X. Huang, Y. Jing, J. Yang, J. Ju, R. H. Cong, W. L. Gao,* T. Yang,* “Flower-like Nanostructure MNb2O6 (M = Mn, Zn) with High Surface Area: Hydrothermal Synthesis and Enhanced Photocatalytic Performance” Mater. Res. Bull. 2014, 51, 271-276.
15) J. Yang, M. F. Yue, J. Ju, R. H. Cong, W. L. Gao,* T. Yang,* “Co-molten solvothermal method for synthesizing chalcopyrite CuFe1-xCrxS2 (x ≤ 0.4): high photocatalytic activity for nitrate ions reduction” Dalton Trans. 2014, 43, 15385-15390.
16) W. L. Gao, Y. Jing, J. Yang, Z. Y. Zhou, D. F. Yang, J. L. Sun, J. H. Lin, R. H. Cong,* T. Yang,* “Open-framework Gallium Borate with Boric and Metaboric Acid Molecules inside Structural Channels Showing Photocatalysis to Water Splitting” Inorg. Chem. 2014, 53, 2346-2366
17) D. F. Yang, Y. Jing, Y. Zhang, X. M. Liu, Z. S. Lin, R. H. Cong,* W. L. Gao,* T. Yang, “CdB10O14(OH)4?H2O with an unprecedented decaborate fundamental building block”, Mater. Res. Bull. 2013, 48, 270-276.
18) D. F. Yang, R. H. Cong, W. L. Gao,* T. Yang,* “Boric acid flux synthesis, structure and magnetic property of MB12O14(OH)10 (M = Mn, Fe, Zn)”, J. Solid State Chem. 2013, 201, 29-34.
19) W. L. Gao, Y. X. Wang, G. B. Li, F. H. Liao, L. P. You, J. H. Lin*, Synthesis and Structure of an Aluminum Borate Chloride Consisting of 12-Membered Borate Rings and Aluminate Clusters, Inorg. Chem. 2008, 47, 7080–7082
20) W. L. Gao, T. Yang, Y. X. Wang, G. B. Li, Fuhui Liao, J. H. Lin,* Synthesis, characterization and catalytic performance of Cr-incorporated Aluminoborate octahedral molecular sieves, J. Phys. Chem. B, 2005, 109, 22775-22779
21) W. L. Gao, R. C. Jin, J. X. Chen, H. S. Zeng, F. X. Zhang, N. J. Guan,* Titania-Supported Bimetallic Catalysts for Photocatalytic Reduction of Nitrate, Catal. Today, 2004, 90, 331-336
22) W. L. Gao, X. X. Guan, J. X. Chen, R. C. Jin, F. X. Zhang, N. J. Guan,* Catalytic reduction of nitrite ions in drinking water over Pd-Cu/TiO2 bimetallic catalyst, Cataly. Today, 2004, 93-95 C, 331-337
23) W. L. Gao, N. J. Guan,* J. X. Chen, H. S. Zeng, Z. G. Liu, Titania Supported Pd-Cu Bimetallic Catalyst for the Reduction of Nitrate in Drinking Water, Appl. Catal. B: Environ., 2003, 46, 341-351
24) W. L. Gao, R. C. Jin, J. X. Chen, F. X. Zhang, Z. G. Liu, N. J. Guan,* Titania Supported Pd-Cu Bimetallic Catalyst for the Reduction of Nitrite in Drinking Water, Catal. Lett., 2003, 91, 25-30
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